(E)-4-(2-(7-Bromo-[1,2,5]thiadiazolo[3,4-c]pyridin-4-yl)vinyl)-N,N-diphenylaniline
نویسندگان
چکیده
(Diphenylamino)phenylethenyl group-containing chromophores are widely employed to design effective materials with useful electronic properties. In this communication, (E)-4-(2-(7-Bromo-[1,2,5]thiadiazolo[3,4-c]pyridin-4-yl)vinyl)-N,N-diphenylaniline was regioselectively obtained by the Heck reaction of 4,7-dibromo-[1,2,5]thiadiazolo[3,4-c]pyridine N,N-diphenyl-4-vinylaniline. The structure newly synthesized compound established means elemental analysis, high resolution mass-spectrometry, 1H, 13C, NOESY NMR, IR and UV spectroscopy mass-spectrometry.
منابع مشابه
(E)-4-Bromo-N-{(E)-3-[(4-bromo-2-methylphenyl)imino]butan-2-ylidene}-2-methylaniline
The title compound, C(18)H(18)Br(2)N(2), is centrosymmetric with the mid-point of the central C-C bond of the butyl group located on an inversion center. The terminal benzene ring is approximately perpendicular to the central butyl plane [dihedral angle = 71.9 (8)°]. No hydrogen bonding or aromatic stacking is observed in the crystal.
متن کامل(E)-4-Bromo-N′-(2-chlorobenzylidene)benzohydrazide
In the title compound, C(14)H(10)BrClN(2)O, the dihedral angle between the two benzene rings is 11.4 (2)°. In the crystal structure, mol-ecules are connected via inter-molecular N-H⋯O hydrogen bonds into one-dimensional chains running parallel to the c axis.
متن کامل(E)-4-Bromo-N-(2-chlorobenzylidene)aniline
In the title Schiff base mol-ecule, C(13)H(9)BrClN, the dihedral angle between the benzene rings is 49.8 (2)° and the mol-ecule has an E configuration about the C=N bond. In the crystal, there are no directional interactions but only van der Waals inter-molecular inter-action forces between neighbouring mol-ecules.
متن کامل(E)-4-Bromo-N′-(2-nitrobenzylidene)benzohydrazide
The title compound, C(14)H(10)BrN(3)O(3), was obtained by a condensation reaction between 2-nitro-benzaldehyde and 4-bromo-benzohydrazide. The dihedral angle between the two benzene rings is 4.1 (2)°. The mol-ecule displays an E configuration about the C=N bond. In the crystal, mol-ecules are linked into a chain along [100] by inter-molecular N-H⋯O hydrogen bonds.
متن کامل(E)-4-Bromo-2-[(4-ethylphenyl)iminomethyl]phenol
In the title compound, C(15)H(14)BrNO, the dihedral angle between the two benzene rings is 43.99 (2)°. The mol-ecular conformation is influenced by an intra-molecular O-H⋯N hydrogen bond.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Molbank
سال: 2022
ISSN: ['1422-8599']
DOI: https://doi.org/10.3390/m1368